Controlled/Living Radical Polymerization. Progress in ATRP, by Krzysztof Matyjaszewski (Eds.)

By Krzysztof Matyjaszewski (Eds.)

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G. acrylates). A t the same time, there are so many interesting structures to be prepared by C R P that this technique should find commercial use and many new industrial applications in the very near future. ch001 controlled/living radical polymerization. Acknowledgments. The financial support from NSF, E P A and A T R P Consortium Members is gratefully acknowledged. References 1. Matyjaszewski, K. Controlled Radical Polymerization; Matyjaszewski, K . , 1998; Vol. 685. 2. Matyjaszewski, K . ; Müller, Α.

Fischer, H . J. Polym. Sci. : Polym. Chem. 1999, 37, 1885. 78. ; Howell, Β. ; Matyjaszewski, K . ; Smith, P. ; Priddy, D . B . Macromolecules 1995, 28, 6692. 79. ; Fukuda, T. Macromolecules 1997, 30, 2503. 80. ; Solomon, D . Polym. Bull. 1982, 6, 589. 81. Matyjaszewski, K . ; Patten, T. ; Xia, J. J. Am. Chem. Soc. 1997, 119, 674. 82. Shipp, D . ; Matyjaszewski, K . Macromolecules 1999, 32, 2948. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2000. ch003 Institut für Physikalische Chemie der Georg-August-Universität, Tammannstrasse 6, D-37077 Göttingen, Germany A n almost constant value of chain-length averaged termination rate coefficient, k , is observed during the initial period of free-radical homo- and copolymerizations in bulk and in solution with the extension of this plateau region depending on monomer type and on the particular polymerization conditions.

Medsker, R. ; Rinaldi, P. ; Tung, D . S. Macromol. Symp. 1996, 111, 25. 23. Espenson, J. H. Acc. Chem. Res. 1992, 25, 222. 24. Matyjaszewski, K . ; Wang, J. S. Macromolecules 1995, 28, 2093. 25. Moad, C. L . ; Rizzardo, E . ; Tang, S. H. Macromolecules 1996, 29, 7717. 26. ; Chong, Y. K. B . ; Le, T. P. ; Mayadunne, R. T. ; Meijs, G . ; Moad, C. L . ; Rizzardo, E . ; Thang, S. H. Macromolecules 1998, 31, 5559. 27. ; Müller, Α. Η. E . Macromolecules 1997, 30, 1253. 28. Fischer, H . J. Polym. , Part A: Polym.

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